Screening tests for hydrogen stress cracking susceptibilityw. Environmentally assisted cracking eac is a general term that includes processes such as stress corrosion cracking scc, hydrogen embrittlement he, sulfide stress cracking ssc, liquid metal embrittlement lme, and corrosion fatigue cf. Jul 25, 2017 sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. H2s can cause sulfide stress cracking of stainless steels. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogen induced cracking hic, describes the embrittling of metal after being exposed to hydrogen. Hydrogen induced cracking hic and sulfide stress cracking ssc are two hydrogen embrittlement phenomena that can fracture steel 5, 6. Sulfide stress cracking of nickelcontaining lowalloy. Abstract it is generally accepted that sulfide stress cracking ssc failures are the result of hydrogen embrittlement. Section page tables iii figures iv definitions v acronyms vi foreword vii 1. Sulfide stress cracking of nickelcontaining lowalloy steels. Hydrogen embrittlement cracking of superduplex steel twi.
Hydrogen embrittlement he a permanent loss of ductility in a metal or alloy caused b y hydrogen in combination with stress, either externally applied or internal residual stress 1. Hydrogen cracking of ferriticaustenitic stainless steel weld. This is a type of deterioration which can be linked to corrosion and corrosioncontrol processes. Since it is generally accepted that cracking in sour environments involves hydrogen embrittlement, particularly for the constructional steels, it may be of value to. Hydrogen embrittlement is the process by which various metals, most importantly highstrength steel, become brittle and fracture following exposure to hydrogen. Hydrogen cracking of ferriticaustenitic stainless steel. Hydrogen embrittlement of steel industrial metallurgists. Sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. Introduction in the year 1875, johnson 1 revealed extraordinary changes in the tough. Sulfide stress cracking is a form of hydrogen embrittlement that occurs in high strength steels and in localized hard zones in weldment of susceptible materials. Hydrogen atoms can diffuse into metals, making them brittle. The iron sulfide is cathodic to steel, contributing to pitting corrosion of scalefree areas. Hydrogen atoms diffuse readily into steel during processes such as acid pickling, electroplating, arc welding with moist or wet electrodes, and exposure to hydrogen sulfide.
Sulfide stress cracking an overview sciencedirect topics. Mechanics of hydrogen diffusion and embrittlement duration. There are maximum acceptable h 2 s concentration limits in sale quality oil and gas, which require. Sulfide stress cracking of super cr martensitic stainless steel. Hydrogen sulfide is a colorless, very poisonous, flammable gas with the characteristic foul odor of rotten eggs. Hydrogen embrittlementsulfide stress cracking h2s metal. It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement. Cold work effects on sulfide stress cracking of pipeline steel exposed to sour environments.
Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. Hydrogen embrittlement is often the result of unintentional introduction of hydrogen into susceptible metals during forming or finishing operations. The effects of sulfide stress cracking on the mechanical properties. Hydrogen sulfide cracking of carbon and alloy steels. The major hazards of h 2 s are its ability to cause rapid damage to health or sudden death due to accidental exposure and metal integrity failure due to general corrosion or cracking. Hydrogeninduced cracking susceptibility in highstrength. Sulfide stress cracking of high strength modified crmo steels. Stress cracking is a form of hydrogen embrittlement.
Sulfide stress cracking ssc occurs at locations where atomic hydrogen is able to diffuse at sites of high internal stress, such as grain boundaries, inclusions and regions of triaxial stress at notches. The role of hydrogen in sulfide stress cracking of low. All materials susceptible to hydrogen embrittlement are also very susceptible to stress corrosion cracking. Hydrogen embrittlement and stress corrosion cracking. Hydrogen sulphide stress corrosion cracking in materials for.
Dec 19, 2019 sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. In he as most people use the term, hydrogen is already present in the metal, eg from melting, pickling, etc. This article discusses hydrogen embrittlement of carbon steel. This is the embrittlement caused by the absorption of hydrogen sulfide. Basically, stress corrosion cracking susceptibility is a function of hydrogen sulfide concentrations, alloy compositions, hydrogen sulfide partial pressure, residual and applied stresses, and temperature. Sulfide stress cracking ssc has been the subject of investigation since the late 1940s, when a mysterious form of brittle failure began to be observed in steel equipment used to produce oil and. Sulfide stress cracking is a form of hydrogen embrittlement that occurs in highstrength steels and in localized hard zones in weldment of susceptible. Crack initiation may be due to the reduction in true fracture stress which accompanies hydrogen entry into steel. Sulfide stress cracking of super cr martensitic stainless steel localized corrosion and hydrogen embrittlement influences. This includes a discussion of the mechanism by which a steel becomes embrittled by hydrgogen, circumstances that lead to embrittlement, the effects of embrittlement on steel behavior, how to prevent the embrittlement, and tests for evaluating whether a steel has been embrittled.
The risk of hydrogen embrittlement of steels is a primary concern for material development in oil and gas production. Hydrogeninduced cracking hic and sulfidestress cracking ssc are two hydrogen embrittlement phenomena that can fracture steel 5, 6. Hydrogen embrittlement associated with strain localization in a precipitationhardened femnalc light weight austenitic steel hydrogen embrittlement of a precipitationhardened fe26 mn11 al1. How to assess the susceptibility of an alloy steel to low temperature hydrogen damages such as hydrogen blistering hb, hydrogen induced cracking hic, stress oriented hydrogen induced cracking sohic, stepwise cracking swc, hydrogen embrittlement he, hydrogen stress cracking hsc, sulfide stress cracking ssc, and soft zone cracking. Sulfide stress cracking is a function of hydrogen sulfide concentration as low as ppm, hydrogen sulfide partial pressure, stresses, material yield strength, temperature and ph. Sulfide stress cracking is the cracking of a metal under the combined action of tensile stress and corrosion in the presence of water and hydrogen sulfide a form of hydrogen stress cracking. It is also explained that how to test the damage due to hydrogen embrittlement in stainless steel.
It explains how hydrogen embrittlement occurs in stainless steel. It was postulated that the time to failure may be related to the time required for hydrogen to diffuse into the steel and reduce ductility sufficiently to allow crack propagation. The role of hydrogen in sulfide stress cracking of low alloy. Hydrogen embrittlement is not sensitive to composition, but to the strength level of the steel, the problem being most pronounced in high strength alloy steels. When placed in proximity to tensile stresses, embrittlement and the beginnings of brittle fracture may occur. Sulfide stress cracking is the worst type of corrosion in the presence of hydrogen sulfide. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. Hydrogen embrittlement as discussed earlier sulfide stress cracking. It is generally accepted that sulfide stress cracking ssc failures are the result of hydrogen embrittlement. The test focuses on hydrogen embrittlement of copper alloys, including a metallographic evaluation method a, testing in a hydrogen charged chamber followed by metallography method b, and method c is the same as b but includes a bend test. At present there are two main theories for sulfide corrosion cracking, namely hydrogen embrittlement mechanism and stress corrosion cracking mechanism. Effect of temperature in hydrogen embrittlement in stainless steel, and fusion in inox steel. After stressing, delayed brittle fracture may occur, particularly in higherstrength steels.
Sulfide stress cracking is also environmentally produced so you have a delay until the sulfide environment causes hydrogen entry into the metal. Wet hydrogen sulfide h2s cracking inspectioneering. Types of corrosion materials selection guide swagelok. Fabrication hydrogen cracking in sma 22%cr duplex stainless steel weld deposits may be avoided by maintaining a weld metal phase balance of less than 60% ferrite and a deposit hydrogen content of less than 18mlh 2 stp100g. Hydrogen stress cracking is a form of hydrogen embrittlement that occurs when corrosion from acids like wet hydrogen sulfide and hydrofluoric acid cause atomic hydrogen to penetrate hardened or higher strength steels and cause stress cracking.
Generally, hydrogen embrittlement is classified under two broad categories based on the. There are several forms of embrittlement in steel like. In a previous post, we discussed the broad differences between anodic and cathodic forms of environmentally assisted cracking eac. In the presence of water and hydrogen sulfide, atomic hydrogen is produced and enters the steel, recombining at discontinuities to form molecular gases hydrogen gases. Carbon and low alloy steels which are subjected to sour service environments may be susceptible to hydrogen induced cracking hic. Hydrogen sulfide hsub 2s has long been associated with the cause of corrosion damage and sulfide stress cracking ssc in high strength steels and high hardness weldments used in oil and gas production, petroleum refining, and petrochemicalchemical processing. Sulfide stress cracking behavior of a martensitic steel. Hydrogen sulfide cracking of carbon and alloy steels corrosion. The influence of composition, heattreatments, and microstructure of quenched and tempered crmo steels on their behavior under sulfide stress corrosion cracking is studied. Pdf hydrogen sulfide stress corrosion cracking of high.
Sulfide stress cracking of steels it is generally accepted that ssc is a form of hydrogen embrittlement cracking in most high strength steels. This penetration can lead to the brittle fracture of materials that are normally ductile when hydrogen happens to be present in their environment. In this chapter the terms eac and scc are generally interchangeable. There are numerous astm standards for testing for hydrogen embrittlement. Hydrogen induced cracking can occur if the metal is subject to static or cyclic tensile stress. Two superduplex stainless steel hubs on a subsea manifold subject to cathodic protection failed as a result of hydrogen embrittlement stress corrosion cracking. Hydrogen induced cracking hic is a form of tiny blistering damage caused by a high concentration of hydrogen in steel. This article explains all about hydrogen embrittlment in stainless steel. Transverse sections of steels showing ssc cracks, after corrosion testing. Ssc is especially prevalent in iron alloys because of the restricted slip capabilities in. The effect of sulfide inclusions on the susceptibility of steels to pitting, stress corrosion cracking and hydrogen embrittlement. High strength 244,000 psi ultimate tensile strength cold drawn carbon steel wire is susceptible to cracking in hydrogen sulfide solutions at room temperature at stress levels less than 15% of.
The highstrength, precipitationhardening, stain less steels have varying degrees of resistance to stresscorrosion cracking and hydrogen embrittlement, depending upon strength level and heattreating pro. Most groups of alloys can exhibit failure by cracking in. Initial theories that ssc was a form of stress corrosion cracking eventually gave way to the current understanding that the phenomenon is caused by hydrogen embrittlement. Is sulfide stress cracking an anodic or a cathodic process. It should not be confused with the term stress corrosion cracking which is. How to assess the susceptibility of an alloy steel to low temperature hydrogen damages such as hydrogen blistering hb, hydrogeninduced cracking hic, stressoriented hydrogeninduced cracking sohic, stepwise cracking swc, hydrogen embrittlement he, hydrogen stress cracking hsc, sulfide stress cracking ssc, and soft zone cracking. A series of tests was performed to establish the threshold condition for cracking. Nanostructured steel susceptibility to sulfide stress cracking. However, the evidence heretofore has been mostly circumstantial. While the role of hydrogen sulfide in promoting increased levels of hydrogen in steels was recognized early on, researchers disagreed on the mechanism responsible for ssc. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. Pdf sulfide stress corrosion cracking and hydrogen induced. This term should not be confused with stress corrosion cracking scs, since this is anodic in nature. The factors of hydrogen embrittlement and ways to prevent it is.
Astm b577 is the standard test methods for detection of cuprous oxide hydrogen embrittlement susceptibility in copper. The embrittlement of a metal or alloy by atomic hydrogen involves the ingress of hydrogen into a component, an event that can seriously reduce the ductility and loadbearing capacity, cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials. This is an embrittlement that is caused by liquid metals. The most common forms of wet h 2s cracking are hydrogen induced cracking hic, stressoriented hydrogen induced cracking sohic, and sulfide stress cracking ssc. Stress corrosion cracking and hydrogen embrittlement of. A pitting type corrosion and sulfide stress cracking ssc. It should not be confused with the term stress corrosion cracking which is an anodic. Admittedly, direct evidence to this effect is limited. Susceptible alloys, especially steels, react with hydrogen sulfide, forming. In that article, we concluded that while localized corrosion appears to be a prerequisite for anodic eac modes such as stress corrosion cracking scc, hydrogen assisted eac mechanisms like hydrogen stress cracking hsc are exacerbated at cathodic potentials. The purpose of this paper is to provide the experimental evidence which establishes the causality of hydrogen and the contributory roles of h 2 s and anodic dissolution.
This is an embrittlement caused by diffusion of metal atoms, either liquid or solid. The influence of chemical composition and microstructure of api linepipe steels on hydrogen induced cracking and sulfide stress corrosion cracking. Hydrogen embrittlement assisted cracking hec continues to be a significant concern for many major industries 14. Sulfide stress cracking is a form of hydrogen embrittlement that occurs in highstrength steels and in localized hard zones in weldment of susceptible materials when the environment contains wet h 2 s. This is termed sulfide stress cracking ssc and is more. Highstrength steels with improved sulfide stress cracking resistance. Sulfide stress cracking mostly occurs in very highly acidic environments. In the presence of water and hydrogen sulfide, atomic hydrogen is produced and enters the steel, recombining at discontinuities to. Corrosionpedia what is sulfide stress cracking ssc. Effect of microstructure and crystallography on sulfide. Sulphide stress cracking is prevented by minimising the hardness and strength of the alloys used for wet h2s systems. A bent beam test method for hydrogen sulfide stress corrosion cracking reslstanced. It involves the ingress of hydrogen into a component, an event that can seriously reduce the ductility and loadbearing capacity, cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials.
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